Organic%20Synthesis%20and%20Polymerization%20Processes%20Lab

Organic Synthesis and Polymerization Processes Lab

RESEARCH FIELDS:

Chemistry of Heterocyclic and High Molecular Weight Compounds

ONGOING PROJECTS:

State-funded Project by the Ministry of Science and Higher Education

(Agreement № № 075-03-2020-176/3; code at the Parus 8 System FZZE-2020-0022)

Grant (financed by the Russian Foundation for Basic Research and the Government of the Irkutsk region, Project № 20-43-383003)

Grant 20-33-90023 (Russian Foundation for Basic Research)

(Agreement 20-33-90023\20)

“Experimental and Theoretical Research on Structure, Reactivity of Catalytic and Physicochemical Properties as well as on Methods for Synthesis Pd-, Ni, and Cr-containing Metal Complexes, Nanoparticles, Polymers, and Materials: New Catalytic Systems, Functionalized Polymeric and Bimetallic Materials, Including Amphiphilic, Biocompatible, and Hybrid”

“NH-substituted 5-amino-1,2,3-triazole-4-carboxamide and its derivatives: scaffold-oriented synthesis in the design of bioactive heterocyclic assemblies”

“Creating New Biodegradable Polyelectrolytes by Modifying Polysaccharides”

ACHIEVED OUTCOMES:

The main regularities of macromolecular reactions (reactive blending) involving natural and synthetic polymers containing randomly arranged reactive "anchor" functional fragments in their structure have been identified
The capabilities of molecular design of "conetworks" (block copolymer meshes) formed as a result of reactive blending have been demonstrated
The concept for using polymers blending of different nature to create hydrogel systems capable of directionally changing their properties under varying environmental parameters has been set

THE LIST OF TOP SCIENTIFIC PUBLICATIONS:

Sokolnikova T.V., Proidakov A.G., Kizhnyaev V.N. Organocatalytic Enamine–Azide Addition Reaction in the Synthesis of 1,4,5-Trisubstituted 1,2,3-Triazoles // Russ. J. Org. Chem.2021. V. 57. No 3. P. 376–382
Kizhnyaev V.N., Pokatilov F.A., Akamova E.V. Synthesis and Properties of Network Paired Polymers Based on Poly(N-vinylpyrrolidone) // Polymer Science, Series B. 2020. V. 62. No. 5. Р. 483–490.
Kizhnyaev V.N., Pokatilov F.A., Shabalin A.I., Zhitov R.G. Conetworks on the Base of Polystyrene with Poly(methyl methacrylate) Paired Polymers // e-Polymer. 2019. V. 19. P. 421-429.
Kizhnyaev V.N., Pokatilov F.A., Vil`yanen D.V., Gross V.I. and Edel`shtein O.A. Network Paired Polymers Base on Poly(acrylic acid) // Polymer Science, Ser. B, 2018. V. 60. No. 1. P. 99–106.
Kizhnyaev, V. N.; Golobokova, T. V.; Pokatilov, F. A.; Vereshchagin, L. I.; Estrin, Ya. I.
Synthesis of energy-intensive triazole- and tetrazole-containing oligomers and polymers (review) // Chem. Heterocycl. Compd. 2017. V. 53. P. 682.