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catlab catlab

CATALYSIS LABORATORY (CATLAB)

 RESEARCH FIELDS:

  • Metal Complex and Nanoparticle Hydrogenation Catalysts
  • Di-, Oligo-, Poly- Telomerization of Unsaturated Compounds
  • Coordination Chemistry of Palladium and Nickel

ONGOING PROJECTS:

State-funded Project by the Ministry of Science and Higher Education

(Agreement № 075-03-2020-176/3,

code at Parus 8 System FZZE-2020-0022)

Grant №20-33-70139 (Russian Foundation for Basic Research)

Grant № 19-73-00046 (by the Russian Science Foundation)

“Experimental and Theoretical Research on Structure, Reactivity of Catalytic and Physicochemical Properties as well as on Methods for Synthesis Pd-, Ni, and Cr-containing Metal Complexes, Nanoparticles, Polymers, and Materials: New Catalytic Systems, Functionalized Polymeric and Bimetallic Materials, Including Amphiphilic, Biocompatible, and Hybrid”, supervisor Shmidt A.F.

“New Complexes of Palladium, Nickel, and Chromium with Various Polydentate S, Se- N-, O-containing Organic Ligands: Synthesis, Structure, and Catalytic Properties”, supervisor Suslov D.S.

“Developing of Catalyst Systems based on Palladium and Nickel Complexes for Telomerization and Hydrofunctionalization of 1,3-Dienes”, supervisor Bykov M.V.

ACHIEVED OUTCOMES:

  • New approaches to synthesis of effective (active and selective) palladium catalysts for hydrogenation of unsaturated compounds modified with elemental phosphorus has been developed
  • Mechanism of formation, size, chemical and phase composition of Pd-P particles, state of their surface layer, causes of modifying action of phosphorus in hydrogenation of nitrohalogenarenes, mono- and disubstituted alkynes, alkynols, and alkyl-anthraquinones have been set by the physical & chemical methods
  • The main stages of the processes of formation, functioning, deactivation and regeneration of catalytically active complexes of lower alkenes oligomerization in Ziegler-type systems have been established

THE LIST OF TOP SCIENTIFIC PUBLICATIONS:

  1. Role of phosphorus in the formation of selective palladium catalysts for hydrogenation of alkylanthraquinones / L.B. Belykh, N.I. Skripov, T.P. Sterenchuk, V.V. Akimov, V.L. Tauson, T.A. Savanovich, F.K. Schmidt // Applied Catalysis A, General. – 2020. – Vol. 589. 117293 (https://doi.org/10.1016/j.apcata.2019.117293.)
  2. The effect of crystallinity on selectivity of palladium catalysts in hydrogenation of 2-ethyl-9,10-anthraquinone / L.B. Belykh, N.I. Skripov, T.P. Sterenchuk, F.K. Schmidt // Catalysis Communications. – 2020. – Vol. 146. – 106124. (https://doi.org/10.1016/j.catcom.2020.106124)
  3. Pd-P nanoparticles as active catalyst for the hydrogenation of acetylenic compounds / L.B. Belykh, N.I. Skripov, T.P. Sterenchuk, K.L. Gvozdovskaya, S.B. Sanzhieva, F.K. Schmidt // J. Nanopart. Res. – 2019. – Vol. 21. № 9. – P. 198−213. (https://doi.org/10.1007/s11051-019-4641-z).
  4. Synthesis of mono- and dinuclear palladium(II) complexes containing oxadithioether ligands and their catalytic activities in norbornene polymerization / D.S. Suslov, Z.D. Abramov, I.A. Babenko, V.A. Bezborodov, T.N. Borodina, M.V. Bykov, M.V. Pakhomova, V.I. Smirnov, A.V. Suchkova, G.V. Ratovskii, I.A. Ushakov, A.I. Vilms // Appl. Organomet. Chem. — 2021. — P. e6381. — DOI:10.1002/aoc.6381.
  5. Cationic palladium(II)–acetylacetonate complexes containing phosphine and aminophosphine ligands and their catalytic activities in telomerization of 1,3-butadiene with methanol / D.S. Suslov, M.V. Bykov, Z.D. Abramov, I.A. Ushakov, T.N. Borodina, V.I. Smirnov, G.V. Ratovskii, V.S. Tkach // J. Organomet. Chem. — 2020. — V. 923. — P. 121413. — DOI:10.1016/j.jorganchem.2020.121413.
  6. Polymerization of phenylacetylene by cationic acetylacetonate palladium complexes / D.S. Suslov, M.V. Pakhomova, M.V. Bykov, I.A. Ushakov, V.S. Tkach // Catal. Commun. — 2019. — V. 119. — P. 16–21. — DOI:10.1016/j.catcom.2018.10.010.

PRIMARY INVESTIGATORS

Professor, Doctor of sciences (Chemistry)
Schmidt Fedor

Leading researcher

Scientific interests: Catalysis of hydrogenation, di- and oligomerization of alkenes by transition metal complexes, Mechanism of formation, functioning, deactivation and regeneration of catalytically active particles, Kinetic and spectral methods of investigation

Web of Science

Scopus

ORCID

What we know is not much. What we don't know is enormous - P. Laplace

Professor, Doctor of sciences (Chemistry)
Belykh Lyudmila

Leading researcher

Scientific intrests: Metal complex and nano-sized catalysis, Hydrogenation of unsaturated compounds, Mechanism of formation and functioning of palladium-containing nanoparticles, Electron microscopy, X-ray photoelectron spectroscopy

Web of Science

Scopus 

ORCID

There is neither talent nor genius without hard work – D.I. Mendeleev

Doctor of sciences (Chemistry)
Suslov Dmitry

Leading researcher

Scientific intrests: Metal complex catalysis, catalytic oligo- and polymerization of unsaturated compounds, Coordination chemistry of palladium and nickel compounds

Web of Science

Scopus 

ORCID